Process and Mechanisms of Deep Fluid Effects on Hydrocarbon Generation and Pore Space in Shale: A Case Study from the Mesoproterozoic Xiamaling Formation in the Zhaojiashan Section     

MENG Qingqiang  PANG Qian  HU Guang  JIN Zhijun  ZHU Dongy  LIU Jiayi  ZHANG Chuanwen 《《地质学报》英文版》2022,96(4):1342-1352

Heat carried by deep fluid might greatly affect hydrocarbon generation and pore space in shale. Dyke intrusion carrying high levels of heat may be a means by which to explore the influence of deep fluid on shale reservoirs. This study evaluates hydrocarbon generation and analyzed the evolution of shale storage space in the third member of the Xiamaling Formation in the Zhaojiashan section, Hebei Province, based on experimental data such as TOC, SEM, VRo, low-temperature N2 adsorption and high-pressure mercury injection. The results show that the dyke intrusion reduced the shale TOC content drastically―by up to 77%―and also induced instantaneous hydrocarbon generation over a range about 1.4 times the thickness of the intrusion. Furthermore, the dyke intrusion might transform organic pores in surrounding shales into inorganic pores. There were two shale porosity peaks: one appeared when VRo = 2.0%, caused by the increase of organic pores as thermal maturity increased, the other occurred when the VRo value was between 3% and 4%, caused by the increase of inorganic mineral pores. It can be concluded that dyke intrusion can be an effective tool with which to study how deep fluid affects instantaneous hydrocarbon generation and pore space in shale.  相似文献   

Petrogenesis and Tectonic Implications of A-type Granites in Zhaheba in the East Junggar Region of Xinjiang, China: Evidence from Geochronology, Geochemistry and Sr-Nd Isotopic Compositions     

TANG Hejun  MENG Guixiang  WU Zhenhan  WANG Zhaolin  DENG Zhen  YAN Jiayong  QI Guang  XUE Ronghui 《《地质学报》英文版》2022,96(3):938-953

The magma source, petrogenesis, tectonic setting and geochronology of the late Paleozoic A-type granites widely exposed in the Zhaheba area, East Junggar, have thus far not been well-constrained. A better understanding of these issues will help to reveal the magmatic processes and continental growth of Central Asia. The A-type granites in Zhaheba include the Ashutasi alkaline granites and the Yuyitasi syenogranites, which were emplaced at 321.5 ± 4.8 Ma and 321.7 ± 0.6 Ma, respectively. The major rock-forming minerals are orthoclase, perthite, arfvedsonite and quartz, which exhibit the following principal geochemical characteristics of A2-type granites. (1) Their REE distribution curves each exhibit a ‘V’-shaped pattern and a marked depletion in Eu. They are rich in large-ion lithophile elements Rb, Th and U as well as high-field-strength elements Nb, Ta, Zr and Hf, but significantly depleted in Ba, Sr, P and Ti. (2) Their (87Sr/86Sr)i values (0.7021–0.7041), εNd(t) values (4.57–5.16) and REE distribution patterns are in basic agreement with those of the Kalamaili A-type granite belt in East Junggar. The TDM2 values of the alkaline granites and syenogranites range from 661 to 709 Ma. The A-type granites may be the products of upwelling asthenosphere-triggered partial melting of immature lower crust. The alkaline granites were late-stage products of crystallization and differentiation. Compared to the syenogranites, the alkaline granites are significantly lower in K2O, Na2O, Al2O3, FeO, MgO and CaO, but significantly higher in incompatible elements (e.g., SiO2, Rb, and Sr). The magmatic crystallization temperatures of the syenogranites and alkaline granites are 874°C and 819°C, respectively. As their age gradually decreases (peak ages: 322 Ma and 307 Ma, respectively), there is a gradual decrease in the TDM2 of the A-type granites and a gradual increase in the εNd(t) value from the Ulungur belt to the Kalamaili belt in East Junggar. The study of A-type granites is therefore one of the keys to understanding the laws and mechanisms of crustal accretion during the Phanerozoic period, as well as also being of great significance for understanding the Paleozoic accretion.  相似文献   

祁连山地区花岗质岩浆作用及构造演化     

朱小辉  陈丹玲  冯益民  任云飞  张欣 《地学前缘》2022,29(2):241-260

祁连山在构造上是一条经历了多期构造旋回叠加的早古生代复合型造山带,花岗质岩浆作用研究对揭示其构造演化具有重要意义。锆石U-Pb年代学统计结果表明,祁连地区花岗质岩浆活动可以分为7个大的阶段,包括古元古代早期(2 470~2 348 Ma)、古元古代晚期(1 778~1 763 Ma)、中元古代晚期-新元古代早期(1 192~888 Ma)、新元古代中期(853~736 Ma)、中寒武世-志留纪(516~419 Ma),泥盆纪-早石炭世(418~350 Ma)以及中二叠世-晚三叠世(271~211 Ma)。其中古元古代早期发育强过铝质高钾钙碱性S型和准铝质低钾拉斑-高钾钙碱性I型花岗岩,记录了早期的陆壳增生及改造事件。古元古代晚期为准铝质-弱过铝质高钾钙碱性-钾玄质A型花岗岩,是Columbia超大陆裂解事件的产物。中元古代晚期-新元古代早期以过铝质-强过铝质钙碱性-钾玄质S型花岗岩为主,新元古代中期以准铝质-强过铝质钙碱性-高钾钙碱性A型花岗岩为主,分别对应Rodinia超大陆的汇聚和裂解事件。中寒武世-志留纪花岗岩是洋陆转换过程中的产物,约440 Ma加厚基性下地壳部分熔融形成的低Mg埃达克岩的广泛出现指示祁连地区全面进入碰撞造山阶段。泥盆纪-早石炭世花岗岩代表后碰撞伸展阶段岩浆岩组合,发育准铝质-强过铝质低钾拉斑-钾玄质等一系列花岗岩。中二叠世-晚三叠世花岗岩以准铝质-弱过铝质钙碱性-高钾钙碱性I型花岗岩为主,有少量弱过铝质高钾钙碱性A型花岗岩,是宗务隆洋俯冲消减以及碰撞后伸展过程的产物。  相似文献   

广东莲花山花岗岩体锆石U-Pb年龄、地球化学特征及地质意义     

杨航  辛宇佳  李建华  张培星 《地球学报》2022,43(2):211-223

广东莲花山岩体位于莲花山断裂带北部, 由规模巨大的侏罗—白垩纪花岗岩组成。本文对莲花山岩体中部进行了系统的岩石学、地球化学、锆石U-Pb同位素和Lu-Hf同位素研究, 获得片麻状花岗岩、细粒黑云母花岗岩和细-中粒黑云母花岗岩的锆石206Pb/238U年龄分别为(142.5±1.5) Ma(MWSD=3.5, N=30)、(138.9±0.6) Ma(MWSD=1.4, N=30)和(145.5±0.7) Ma(MWSD=1.2, N=28), 表明岩体为晚侏罗至早白垩世岩浆活动的产物。地球化学特征显示岩体为偏铝质-弱过铝质(A/CNK=0.97~1.1)、富碱(K2O+Na2O=6.1 wt%~ 8.1 wt%)、富钾(K2O/Na2O=1.4~1.8), 富集Rb、Th、U、K、Pb, 亏损Ba、Ta、Nb、Sr、P、Ti, 与壳源岩浆特征类似。岩体SiO2含量差异较大(69.5 wt%~80.1 wt%), 高硅样品明显经历一定程度的结晶分异, 属于分异的I型花岗岩。所有样品锆石εHf(t)值均为负值(–4.5 ~ –2.0), 在年龄-εHf(t)图中, 均落入球粒陨石演化线和华夏基底演化线之间, 暗示源岩主要为古老壳源基底物质。在此基础上, 结合区域构造-岩浆记录, 本文认为莲花山花岗岩体的形成与古太平洋板片俯冲后撤(roll back)诱发的弧后扩张作用相关。  相似文献   

青海团宝山花岗岩年代学、地球化学特征及其地质意义     

张保涛  胡兆国  姜晓平  王向伟  孙璐伟  张扬  王小玉  赵晓博  郭伟 《现代地质》2021,35(2):504-513

青海省团宝山花岗岩位于南祁连东段,侵位于古元古代化隆群中。为了解其侵位时代、岩体成因和产出构造环境,利用LA-ICP-MS锆石U-Pb定年和地球化学测试方法对团宝山花岗岩岩体样品进行分析。获得其锆石U-Pb年龄为(776±8) Ma;该岩体SiO₂、Al₂O₃和K₂O含量较高,而FeO^T、MgO和CaO含量较低,K₂O/Na₂O大于1,富集Rb、Th等元素,亏损Ba、Zr等元素,具明显的负铕异常,表现为轻稀土富集型稀土配分模式。该岩体为分异程度较高的过铝质钙碱性岩,具S型花岗岩特征,为晚元古代中期陆陆碰撞的产物;源岩为泥质岩或杂砂岩,侵位后在晋宁运动末期和加里东运动中期经历过岩浆热事件。  相似文献   

塔里木北缘库鲁克塔格地区新元古代花岗岩LA-ICP-MS锆石U-Pb年龄、地球化学特征及其构造意义     

陈邦学  徐胜利  周能武  白权金  李超  张洪深 《现代地质》2021,35(2):477-491

采用LA-ICP-MS法分析了塔里木北缘库鲁克塔格一带二长花岗岩锆石U-Pb年龄,获得该二长花岗岩岩体的年龄为(832.3±3.3)Ma(MSWD=2.8,n=24)。岩石地球化学特征显示,二长花岗岩属于准铝质高钾钙碱性系列,为I型花岗岩。微量元素富集大离子亲石元素(LILE)Ba、K、Sr、U等,亏损高场强元素(HFSE)Nb、Ta、Ti、P等;稀土元素总体含量较低(29.88×10^-6~63.57×10^-6),具有弱Eu正异常(δEu=0.87~1.39),整体配分模式与下地壳一致。结合区域地质背景对岩浆岩地球化学特征进行综合分析,认为二长花岗岩形成于岛弧环境。区域构造演化特征指示832 Ma该区洋壳已经开始俯冲,使得这一地区的地壳加厚,同时地幔柱的上涌加热作用导致古老地壳物质发生部分熔融而形成该期花岗岩。  相似文献   

Geochemistry and Petrogenesis of Late Ediacaran Rare-metalAlbite Granites of the Arabian-Nubian Shield     

Bassam A. ABUAMARAH  Mokhles K. AZER  Paul D. ASIMOW  Habes GHREFAT  Heba S. MUBARAK 《《地质学报》英文版》2021,95(2):459-480

The Abu Dabbab albite granite(ADAG), in the central Eastern Desert of Egypt, hosts the most significant rare metal ore deposit in the northern part of the Neoproterozoic Arabian-Nubian Shield. Here, we report detailed field,petrographic, mineralogical and geochemical investigation of the ADAG, an isolated stock-like granitic body with sharp intrusive contacts against metamorphic country rocks, probably emplaced at about 600 Ma. The fine-grained porphyritic upper unit is a preserved remnant of the shallowly-emplaced apex of the magma chamber, whereas the medium-grained lower unit crystallized at deeper levels under subvolcanic conditions. The peraluminous leucocratic ADAG shares common geochemical characteristics with post-collisional intraplate A-type magmas. In addition to the conspicuous enrichment in Na2 O, the ADAG is remarkable for its anomalous concentrations of Ta, Nb, Li, Hf, Ga, Sn, Zn and heavy rare-earth elements. Nb-Ta minerals in the ADAG are mixed with Fe-Mn oxides, forming black patches that increase in abundance toward of the base of the intrusion. Columbite-tantalite, cassiterite and wolframite are the most important ore minerals.Pronounced negative Eu anomalies(Eu/Eu* = 0.10–0.24) reflect extreme magmatic fractionation and perhaps the effects of late fluid-rock interaction. The ADAG was most likely generated by partial melting of the juvenile middle crust of the ANS as the geotherm was elevated by erosional uplift following lithospheric delamination and it was emplaced at the intersection of lineations of structural weakness. Although formation of the ADAG and its primary enrichment in rare metals are essentially due to magmatic processes, late-stage metasomatism caused limited redistribution of rare metals. Fluid-driven subsolidus modification was limited to the apex of the magma chamber and drove development of greisen, amazonite, and quartz veins along fracture systems.  相似文献   

Comparative Study of Acid and Alkaline Stimulants with Granite in an Enhanced Geothermal System     

XU Jianan  FENG Bo  CUI Zhenpeng  LIU Xiyao  KE Zunsong  FENG Guanhong 《《地质学报》英文版》2021,95(6):1926-1939

The Enhanced Geothermal System (EGS) is an artificial geothermal system that aims to economically extract heat from hot dry rock (HDR) through the creation of an artificial geothermal reservoir. Chemical stimulation is thought to be an effective method to create fracture networks and open existing fractures in hot dry rocks by injecting chemical agents into the reservoir to dissolve the minerals. Granite is a common type of hot dry rock. In this paper, a series of chemical stimulation experiments were implemented using acid and alkaline agents under high temperature and pressure conditions that mimic the environment of formation. Granite rock samples used in the experiments are collected from the potential EGS reservoir in the Matouying area, Hebei, China. Laboratory experimental results show that the corrosion ratio per unit area of rock is 3.2% in static acid chemical experiments and 0.51% in static alkaline chemical experiments. The permeability of the core is increased by 1.62 times in dynamic acid chemical experiments and 2.45 times in dynamic alkaline chemical experiments. A scanning electron microscope analysis of the core illustrates that secondary minerals, such as chlorite, spherical silica, and montmorillonite, were formed, due to acid-rock interaction with plagioclase being precipitated by alkaline-rock interactions. Masking agents in alkaline chemical agents can slightly reduce the degree of plagioclase formation. A chemical simulation model was built using TOUGHREACT, the mineral dissolution and associated ion concentration variation being reproduced by this reactive transport model.  相似文献   

Reservoir Characteristics and Genetic Mechanisms of the Mesozoic Granite Buried Hills in the Deep‐water of the Qiongdongnan Basin,Northern South China Sea     

YOU Li  XU Shouli  MAO Xuelian  ZHONG Ji  JIAO Yaoqi  XIONG Xiaofeng 《《地质学报》英文版》2021,95(1):259-267

Due to its structure,rock and mineral composition,fluid and other factors,the granite Buried Hill Reservoir is highly heterogeneous with a complex longitudinal structure and a reservoir space made up of a combination of dissolution pores and fractures.This paper is based on current understanding of tectonic evolution in the northern part of the South China Sea,in conjunction with the seismic phase characteristics.It is determined that the meshed fault system was formed by three stages of movement-tectonic compression orogeny during the Indochinese epoch,strike-slip compression-tension during the Yanshanian Period,early fracture extension activation during the Himalayan-which controlled the distribution of the Buried Hill Reservoir.Drilling revealed two types of buried hills,faulted anticline and fault horst,their longitudinal structure and the reservoir space type being significantly different.The mineral composition,reservoir space and diagenetic characteristics of the reservoir rocks and minerals were analyzed by lithogeochemistry,micro section and logging etc.,it thus being determined that the Mesozoic rocks of the Songnan Low Uplift in the Qiongdongnan Basin are mainly composed of syenogranite,granodiorite,monzogranite,which is the material basis for the development of the Buried Hill Reservoir.The content of felsic and other brittle minerals is more than 70%,making it easy for it to be transformed into fractures.At the same time,the weathering resistance of granodiorite and monzogranite is weaker than that of syenogranite,which is easily weathered and destroyed,forming a thick sand gravel weathering zone.With increasing depth of burial,weathering and dissolution gradually weaken,the deep acidic fluid improving the reservoir property of internal fractures and expanding the vertical distribution range of the reservoirs.The research results lay a foundation for the exploration of Buried Hill in the deep-water area of the Qiongdongnan Basin.  相似文献   

藏南拉康温泉地质特征及雄曲河谷两岸地热分布不均成因分析     

石圣  赵德军  蒋祥  翁新海  陈伟 《矿物岩石》2021,41(1):106-115

西藏山南地区洛扎县雄曲河拉康段在600 m距离内出露温泉4处,仅1处位于河谷右岸;平硐勘查显示两岸岩性、产状、构造一致,地热异常却仅在左岸平硐内部显著,右岸平硐地热异常不明显。本次研究以此异常为出发点,通过片麻状花岗岩不同切面导热实验、片麻状花岗岩与板岩相同切面导热实验,温泉水δ~2H,δ~(18)O同位素测试分析等方法,探究该处河谷两侧地热异常的成因,得出以下结论:1、该处地热资源为干热岩型地热资源,热源是深部岩浆,氢氧同位素显示温泉热水来源于大气降水;2、片麻状花岗岩平行和垂直片麻理方向存在导热各向异性,当温度恒定时平行于片麻理方向比垂直于片麻理方向温度高5.5%~6.0%;3、河流的下切作用使得两岸岩体覆盖程度存在差异,导致两岸地热异常不均。本次研究成果可以为深切峡谷地区寻找浅层干热岩、干热岩发电与水力发电共同开发提供一定启示。  相似文献